Associated solution model rebuilt

نویسندگان

چکیده

A resolution of the long-standing internal problems associated solution model is presented. consistent version theory constructed by imposing a set mandatory restrictions. The expressions for energy and entropy mixing are modified to ensure quasichemical level precision at high temperatures. Complete integration therefore achieved. ensures significant reduction in number empirical parameters used describe experimental thermodynamic data. new interpretation basic equations suggested. clarifying examples provided.

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ژورنال

عنوان ژورنال: Calphad-computer Coupling of Phase Diagrams and Thermochemistry

سال: 2022

ISSN: ['1873-2984', '0364-5916']

DOI: https://doi.org/10.1016/j.calphad.2022.102408